Advanced Power Plant Chemistry — Track 5

Biological Fouling & Microbiological Control

Module 5.5 — Algae, biofilm, and bacteria in cooling towers: a fouling category with no real boiler-side equivalent, and how biocide programs manage it.

PASS THRESHOLD 80% EST. TIME 20 MIN TRACK 5 / 7
≡ Course IndexModule 32 of 48 · Track 5 — Cooling Water Chemistry
Biofilm Growth
Continuous
without intervention
Biocide Types
Oxidizing / Non-Ox.
alternated for resistance
Under Biofilm
MIC Risk
localized corrosion
TUBE SURFACE BIOFILM — bacteria embedded in extracellular matrix O₂-DEPLETED ZONE UNDER BIOFILM — DIFFERENTIAL AERATION CELL, MIC RISK

Click the biofilm or the oxygen-depleted zone to see its role. A biofilm creates an oxygen-depleted zone underneath it, setting up the same anode/cathode differential from Module 4.1.

Select an element to learn more.

A Category With No Real Boiler-Side Parallel

Module 5.1 flagged biological growth as genuinely new territory in this course. The boiler/feedwater cycle (Tracks 1-4) is a closed, oxygen-controlled, chemically hostile environment to biological growth — recall Module 2.6's oxygen scavengers deliberately drive dissolved oxygen toward zero. Cooling towers are the opposite: warm, sunlit, oxygenated, and in continuous contact with atmosphere, which is close to an ideal environment for algae, bacteria, and fungi.

Biofilm — The Central Concept

Biofilm forms when bacteria attach to a wetted surface and secrete a protective extracellular polymeric matrix, creating a structured community rather than free-floating organisms. Biofilm is more consequential than simple surface slime for two reasons: it's an effective insulator, degrading heat transfer at condenser tubes similarly to scale (Module 5.3), and it creates localized chemistry conditions at the metal surface beneath it — notably oxygen depletion — that can drive microbiologically influenced corrosion (MIC), a distinct corrosion category from anything in Track 4 but following the same anode/cathode logic from Module 4.1.

Why biofilm-covered areas become preferential anodes: The area under a biofilm patch is oxygen-depleted relative to the surrounding, more freely oxygenated surface — a differential aeration cell. Following Module 4.1's framework directly, the oxygen-depleted area under the biofilm becomes anodic relative to the well-oxygenated surrounding surface acting as cathode, driving localized corrosion at exactly the spot the biofilm covers.

Algae

Algae growth, driven by sunlight exposure at open cooling tower basins and fill sections, can physically clog tower fill material (reducing cooling efficiency), contribute organic material that feeds bacterial growth, and create slippery surfaces that are a safety concern for personnel accessing tower structures. Algae control typically relies on limiting light penetration where practical and biocide treatment alongside bacterial control.

Biocide Programs

TypeMechanismConsideration
Oxidizing biocides Chlorine, bromine, or similar oxidizers that directly kill organisms through oxidative damage Fast-acting, but can be consumed by other oxidizable material in the water, reducing effectiveness
Non-oxidizing biocides Organic biocide compounds that disrupt specific biological processes (cell membrane, metabolism) Longer-lasting residual, but organisms can develop resistance with prolonged single-product use

Most cooling water biocide programs alternate between oxidizing and non-oxidizing biocides, or use both in combination, specifically to prevent microbial populations from developing resistance to any single treatment approach — a direct parallel to antibiotic resistance management in a medical context, applied here to industrial water systems.

Biocide Interaction With Other Chemistry Programs

Field note: Visible slime or algae is the late-stage, easy-to-notice sign of a biological control program that's already fallen behind. Bacterial count trending, done proactively rather than reactively, catches a developing problem while it's still a dosing adjustment rather than a fouling cleanup project.
Biofilm
A structured community of bacteria attached to a wetted surface and embedded in a self-secreted extracellular polymeric matrix.
Microbiologically Influenced Corrosion (MIC)
Corrosion driven or accelerated by localized chemistry conditions (such as oxygen depletion) created by biofilm or microbial activity at a metal surface.
Differential Aeration Cell
A corrosion cell driven by a difference in oxygen concentration between two areas of the same metal surface, with the oxygen-depleted area becoming anodic.
Oxidizing Biocide
A biocide (such as chlorine or bromine) that kills organisms through direct oxidative damage, fast-acting but consumable by other oxidizable material in the water.
Non-Oxidizing Biocide
An organic biocide compound that disrupts specific biological processes, offering longer residual activity but carrying resistance-development risk with prolonged single-product use.
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